Reaching out to music venues, promoters, licensing companies, etc can be a really daunting task. Some of us are better at asking for things than others, and some of us just may need some help getting organized and coming up with a successful game plan.
Take a look at this really helpful article recently posted on CD Baby's DIY Musician blog, with tips for writing emails that can't be ignored, and how to successfully set yourself up for a YES.
http://diymusician.cdbaby.com/musician-tips/5-steps-pitching-bliss-get-gig-sync-placement/